The short answer is the DC side. The recognised origins of rooftop PV fire are concentrated on the part of the system RC62 keeps returning to: the high-voltage DC strings between the modules and the inverter, and the connectors, isolators and terminations along them. Understanding the mechanism is what makes the design choices make sense rather than feeling like box-ticking.
The DC arc is the core hazard. A string of modules can sit at several hundred volts in daylight, and that voltage is present continuously, with no zero-crossing. When a connection works loose, corrodes, or is poorly made, current can jump the gap and sustain an arc. Unlike an AC fault, a DC arc does not naturally extinguish at a current zero, so it can keep burning at the fault point and ignite the cable, the connector body, or combustible roof build-up around it. This is the failure RC62 and the wider RISCAuthority fire-safety literature are written around, and it is why the guidance treats DC component quality and termination workmanship as fire controls rather than performance details.
Mismatched and contaminated connectors. A large share of field failures trace to DC connectors of different makes mated together, or to connectors crimped on site without the correct tool. They look connected and test fine on day one, then develop resistance, heat and eventually an arc as they weather. A properly engineered array uses one connector type, mated like-for-like, with factory-style crimps, which is one of the plainest things a loss adjuster or insurer surveyor looks for after an incident. Our guide to BS 7671 and solar sets out the wiring-regulation basis for those terminations, and our note on string versus central inverters explains how the choice of architecture changes how many DC connections exist and how far the high-voltage DC runs across the roof.
Why the array stays live matters here too. Because daylight keeps the DC side energised, a fault cannot be cleared by simply switching the building off, and a fire crew cannot assume a dead roof. That is the link between the ignition mechanism and the access and isolation measures: the same live-in-daylight property that drives clear DC isolation also drives the layout decisions a fire service needs.